PRODUCT AND COMPANY IDENTIFICATION

Product Name
:
Copper Telluride
No
:
GSR - SDS 006
Company name
:
PT. Smelting, Gresik Smelter and Refinery
Address
:
Desa Roomo, Kecamatan Manyar PO. Box 555 Gresik 61151 Jawa Timur - Indonesia
Telephone Number
:
62-31-397-6458/59
Fax Number
:
62-31-397-6460

 

TYPICAL COPPER TELLURIDE CONTENT

Chemical Formula
:
Cu2Te
 
ComponentSpecification
Moisture24 %
Au0.0036 %
Ag0.0183 %
Cu37.57 %
Te33.14 g/t
Bi0.09 %
Se0.37 %
As0.18 %
Sb0.01 %
Pb< 0.01
Sn0.02 %
Ni0.11 %
Fe0.02 %

 

HAZARD IDENTIFICATION

Emergency Overview :
Tellurium in melted form are toxic by inhalation and if swallowed. Copper powder is harmful by inhalation and assessed as very toxic to fish and other aquatic organisms and may cause long-term adverse effects in the aquatic environment.

Potential Health Effects

Eyes
:
Contact with eyes may cause slight irritation.
Skin
:
Direct skin contact may result in irritation in some workers.
Ingestion
:
Swallowing this product is suspected to cause toxic effects.
Inhalation
:
Inhaling this product is suspected to cause toxic effects.
Chronic Effects
:
-

 

FIRST AID MEASURES

Eye Contact
:
Rinse with water.
Skin Contact
:
Immediately, take off all contaminated clothing/shoes. Carefully wash the skin for several minutes with soap and water. Contact a doctor if the complaints persist.
Inhalation
:
Fresh air and rest in a warm place. Possibly assisted the patient with respiration. Seek medical advice, even if there are no or only slight symptoms.
Ingestion
:
Give a couple of glasses of water to drink if the person is fully conscious. Contact a doctor if a larger amount has been swallowed.

 

FIRE FIGHTING MEASURES

Fire and Explosion Hazards
:
Elementary tellurium burns slowly in the presence of air, giving a green-blue flame. Dust may form explosive mixtures with air.
Flashpoint and Method
:
Non-flammable and does not support combustion.
Flammable limit
:
Not Applicable.
Autoignition Temperature
:
Not Applicable.
Extinguishing Media
:
Use water spray, alcohol-resistant foam, dry chemical or carbon dioxide.
Fire Fighting
:
Wear self contained breathing apparatus for firefighting if necessary.

 

ACCIDENTAL RELEASE MEASURES

Procedure for Clean Up
Sweep up and shovel. Keep in suitable, closed containers for disposal.

Personal Precaution
Wear appropriate respirator when ventilation is inadequate. Put on appropriate personal protective equipment. Avoid dust formation. Avoid breathing vapors, mist or gas.

Environmental Precaution
Do not let product enter drains.

 

HANDLING AND STORAGE

Handling Precaution
Provide appropriate exhaust ventilation at places where dust is formed. Normal measures for preventive fire protection.

Storage Precaution
Store in cool place. Keep container tightly closed in a dry, well-ventilated place and on waterproof floor. In accordance with preventing of pollution, any spillage should not be discharge into the environment. Symbol and emergency response equipments should be provided in accordance with applicable regulations.

Work/Hygienic Practices
Store the materials away from food, feedstuffs and explosive substances. Always practice good personal hygiene.

 

EXPOSURE CONTROLS/PERSONAL PROTECTION

Eye/Face Protection
:
Use equipment for eye protection tested and approved under appropriate government standards.
Skin Protection
:
Handle with gloves. Gloves must be inspected prior to use. Use proper glove removal technique (without touching glove's outer surface) to avoid skin contact with this product. Dispose of contaminated gloves after use in accordance with applicable laws and good laboratory practices. Wash and dry hands.
Body Protection
:
Choose body protection in relation to its type, to the concentration and amount of dangerous substances, and to the specific work-place. The type of protective equipment must be selected according to the concentration and amount of the dangerous substance at the specific workplace.
Respiration
:
Use respirators and components tested and approved under appropriate government standards

 

PHYSICAL AND CHEMICAL PROPERTIES

Appearance
:
Grey Powder
Odour
:
None
Physical State
:
Solid
Vapour Density
:
Not Applicable
Boiling Point/Range
:
Not Applicable​
Melting Point/Range
:
Not Applicable
Solubility
:
Insoluble in water

 

STABILITY AND REACTIVITY

Stability
The product is stable under normal conditions.

Condition to Avoid
No information.

Incompatible Materials
Avoid contact with strong oxidizers. Incandescence occurs when combined with zinc, cadmium, fluorine, chlorine, chlorine trifluoride, chlorine pentafluoride and lithium silicide. Reacts violently with sodium or silver bromate.

Hazardous Decomposition
None.

Hazardous Polymerization
Melted tellurium oxidizes in air into toxic tellurium oxide.

 

TOXICOLOGICAL INFORMATION

Acute toxicity
:
No data available
Skin corrosion/irritation
:
No data available
Serious eye damage/eye irritation
:
No data available
Respiratory or skin sensitization
:
No data available
Germ cell mutagenicity
:
No data available
Carcinogenicity
:
No data available
Reproductive toxicity
:
No data available
Specific target organ toxicity - single exposure
:
No data available
Specific target organ toxicity - repeated exposure
:
No data available
Aspiration hazard
:
No data available

 

ECOLOGICAL INFORMATION

Even small amounts of copper ions are very toxic to aquatic organisms. The potential to form ions from solid metal depends on the particle size and factors in the surrounding environment, such as pH, redox-potential and the amount of organic material. An acidic pH is favouring the solubility of copper compounds. Copper in form of powder, is considered as very toxic to fish and other aquatic organisms.

DISPOSAL CONSIDERATIONS

Recycle, if possible. The generation of waste should be avoided or minimized wherever possible. Dispose of surplus and non-recyclable products via a licensed waste disposal contractor. The classification of the product may meet the criteria for a hazardous waste. Care should be taken when handling emptied containers that have not been cleaned or rinsed out.

TRANSPORT INFORMATION

Transportation is carried out using sealed containers.

REGULATORY INFORMATION

Originally prepared by PT Smelting , April 2020

 

PT Smelting has prepared this material safety data sheet in order to provide product information which will assist our customers in complying government standard.